Synthesis, characterization and 2,5-pyridinedicarboxylic acid interaction of Zinc(II) complexes with N-(4-X-phenyl)pyridine-2-yl -methanimine ligands (X= -Cl and -N(CH3)2)

Received: September 01, 2017; accepted: October 25, 2017

  • Nicole Dinamarca Departamento de Química de los Materiales, Facultad de Química y Biología, Universidad de Santiago de Chile, Av. L. B. O`Higgins 3363, Casilla 40, Correo 33, Santiago Chile.
  • Pedro Levín Departamento de Química de los Materiales, Facultad de Química y Biología, Universidad de Santiago de Chile, Av. L. B. O`Higgins 3363, Casilla 40, Correo 33, Santiago Chile
  • Hugo Muñoz Departamento de Química de los Materiales, Facultad de Química y Biología, Universidad de Santiago de Chile, Av. L. B. O`Higgins 3363, Casilla 40, Correo 33, Santiago Chile
  • Francesco Caruso Vassar College, Department of Chemistry, Poughkeepsie, NY 12604, USA
  • Miriam Rossi Vassar College, Department of Chemistry, Poughkeepsie, NY 12604, USA
  • Juan Guerrero Departamento de Química de los Materiales, Facultad de Química y Biología, Universidad de Santiago de Chile, Av. L. B. O`Higgins 3363, Casilla 40, Correo 33, Santiago Chile
  • Manuel Ignacio Azócar Departamento de Química de los Materiales, Facultad de Química y Biología, Universidad de Santiago de Chile, Av. L. B. O`Higgins 3363, Casilla 40, Correo 33, Santiago Chile. https://orcid.org/0000-0003-1098-4659
Keywords: Zinc(II) complex; X-ray crystal structure; 2,5- pyridinedicarboxylic acid; Benesi-Hilderbrand

Abstract

Two new Zn(II) N-(4-X-phenyl)pyridine-2-yl-methanimine complexes, [Zn(NN´-Cl)Cl2](1) and [Zn(NN´-N(CH3)2)Cl2](2), have been synthesized and characterized by elemental analysis, FT-IR and NMR-1H spectra. The crystal structure of complex 1 was determined by X-ray single crystal diffraction. Experiments performed by Benesi-Hilderbrand method indicate that zinc complexes interact with 2,5-pyridinedicarboxyc acid.

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Published
2017-05-19
How to Cite
Dinamarca, N., Levín, P., Muñoz, H., Caruso, F., Rossi, M., Guerrero, J., & Azócar, M. (2017). Synthesis, characterization and 2,5-pyridinedicarboxylic acid interaction of Zinc(II) complexes with N-(4-X-phenyl)pyridine-2-yl -methanimine ligands (X= -Cl and -N(CH3)2). Communications in Inorganic Synthesis, 5(2), 11-14. Retrieved from https://latinamres.org/ojs-cis/index.php/CIS/article/view/51
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Articles