Mini Review: Tris(dibenzylideneacetone)dipalladium: New Life of the Old Synthon for Pd(0) atom

Received: March 27, 2018; accepted: May 31, 2018

  • Viacheslav I. Sokolov A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia
  • Natalya V. Abramova A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia.
Keywords: Fullerenes, Nanodiamonds, Graphenes, Tungsten-Disulphides Nanotubes, Heterogeneous Catalysts, Cross-Coupling Reactions

Abstract

The history of a unique stable and soluble complex Pd2(dba)3 has been considered starting with the classical oxidative addition and finishing by the modern synthesis of Pd nanoclusters catalysts absorbed on the carbon and non-carbon polymer supports. Coordinatively non-saturated Pd(0) particles are used for constructing nanopalladium clusters immobilised which are active as catalysts in the cross-coupling reactions.

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Author Biographies

Viacheslav I. Sokolov, A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

Professor Viacheslav I. Sokolov is the head of the Laboratory of Organometallic Stereochemistry in the Institute of Organoelement Compounds Russian Academy of Sciences in Moscow. He has graduated from Chemistry Department of Moscow University. During his scientific career he has published around 400 papers in peer-reviewed journals in organic, organometallic, or inorganic chemistry. For 20 years he was been a Member of the Editorial board of the Journal of Organometallic Chemistry.

Natalya V. Abramova, A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia.

Dr. Natalya V. Abramova graduated from the Moscow Institute of Fine Chemical Technology. She has been postgraduate student and got PhD degree in the Institute of Organoelement Compounds Russian Academy of Sciences in Moscow. At present she is working in the area of nanocarbon including chemistry of fullerenes, carbon nanotubes, and related objects. She is investigating the novel method of preparing heterogeneous nanopalladium catalysts for the carbon-coupling reactions.

Published
2018-05-31
How to Cite
Sokolov, V. I., & Abramova, N. V. (2018). Mini Review: Tris(dibenzylideneacetone)dipalladium: New Life of the Old Synthon for Pd(0) atom. Communications in Inorganic Synthesis, 6(1). Retrieved from https://latinamres.org/ojs-cis/index.php/CIS/article/view/53
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Articles